Search results for "water activation"
showing 2 items of 2 documents
Adsorption and Activation of Water on Cuboctahedral Rhodium and Platinum Nanoparticles
2017
Rh and Pt are widely used as the components in heterogeneous catalysts for multiple industrial applications. Because the metals are typically in the form of nanoparticles in real catalysts, it is important to carefully select models for the computational prediction of the catalytic properties. Here we report a first-principles study on the water activation, an important step in numerous catalytic reactions, using the finite-size Rh and Pt nanoparticle models and compare them to the extended surface models. We show that regardless of the model, adsorption and activation of water is practically identical for both metals, whereas the dissociation is energetically more favorable on Rh. The expe…
Integrated design of breeding blanket and ancillary systems related to the use of helium or water as a coolant and impact on the overall plant design
2021
Currently, for the EU DEMO, two Breeding Blankets (BBs) have been selected as potential candidates for the integration in the reactor. They are the Water Cooled Lithium Lead and the Helium Cooled Pebble Bed BB concepts. The two BB variants together with the associated ancillary systems drive the design of the overall plant. Therefore, a holistic investigation of integration issues derived by the BB and the installation of its ancillary systems has been performed. The issues related to the water activation due to the 16N and 17N isotopes and the impact on the primary heat transfer systems have been investigated providing guidelines and dedicated solution for the integration of safety devices…